- 2026-03-22 6mo Rayo Vallecano 0 at Barcelona 1 Ronald Araújo ESP-BARC 0min 1g
- 2025-08-31 1y Barcelona 1 at Rayo Vallecano 1
- 2025-08-31 1y Rayo Vallecano 1 at Barcelona 1
- 2025-02-17 1y Rayo Vallecano 0 at Barcelona 1 Robert Lewandowski ESP-BARC 90min
- 2024-08-27 2y Barcelona 2 at Rayo Vallecano 1 Pedro González López ESP-BARC 90min 1g
- 2023-11-25 2y Barcelona 1 at Rayo Vallecano 1
- 2023-04-26 3y Barcelona 1 at Rayo Vallecano 2 Francisco José García Torres ESP-RAZA 90min
- 2022-08-13 4y Rayo Vallecano 0 at Barcelona 0
- 2022-04-24 4y Rayo Vallecano 1 at Barcelona 0 Iván Balliu Campeny ESP-RAZA 90min yc
- 2021-10-27 4y Barcelona 0 at Rayo Vallecano 1 Radamel Falcao García Zárate ESP-RAZA 76min 1g
- 2021-01-27 5y Barcelona 2 at Rayo Vallecano 1 Frenkie de Jong ESP-BARC 90min 1g
- 2019-03-09 7y Rayo Vallecano 1 at Barcelona 3 Lionel Andrés Messi Cuccittini ESP-BARC 90min 1g
- 2016-03-03 10y Barcelona 5 at Rayo Vallecano 1 Lionel Andrés Messi Cuccittini ESP-BARC 90min 3g
- 2015-03-08 11y Rayo Vallecano 1 at Barcelona 6 Lionel Andrés Messi Cuccittini ESP-BARC 90min 3g
- 2014-10-04 12y Barcelona 2 at Rayo Vallecano 0 Lionel Andrés Messi Cuccittini ESP-BARC 90min 1g
- 2014-02-15 12y Rayo Vallecano 0 at Barcelona 6 Lionel Andrés Messi Cuccittini ESP-BARC 74min 2g
- 2013-03-17 13y Rayo Vallecano 1 at Barcelona 3 Lionel Andrés Messi Cuccittini ESP-BARC 90min 2g 1a
- 2012-10-27 13y Barcelona 5 at Rayo Vallecano 0 Francesc Fàbregas i Soler ESP-BARC 90min 1g 2a
- 2012-04-29 14y Barcelona 7 at Rayo Vallecano 0 Lionel Andrés Messi Cuccittini ESP-BARC 90min 2g 3a
- 2011-11-29 14y Rayo Vallecano 0 at Barcelona 4 Alexis Alejandro Sánchez Sánchez ESP-BARC 71min (sub in 19) 2g
- 2003-05-03 23y Rayo Vallecano 0 at Barcelona 3
- 2001-05-12 25y Rayo Vallecano 1 at Barcelona 5
- 2000-12-15 25y Barcelona 2 at Rayo Vallecano 2
- 1997-01-25 29y Rayo Vallecano 0 at Barcelona 6
- 1996-02-03 30y Barcelona 1 at Rayo Vallecano 1
- 1995-09-22 31y Rayo Vallecano 0 at Barcelona 2
- 1994-04-05 32y Rayo Vallecano 0 at Barcelona 1
- 1993-11-27 32y Barcelona 4 at Rayo Vallecano 2