- 2014-01-24 12y Siena 1 at Fiorentina 2 Marvin Compper ITA-FIJE 90min 1g
- 2013-05-08 13y Fiorentina 1 at Siena 0 Gonzalo Javier Rodríguez ITA-FIJE 90min 1g
- 2012-12-16 13y Siena 1 at Fiorentina 4 Luca Toni ITA-FIJE 90min 2g
- 2012-01-29 14y Siena 1 at Fiorentina 2 Cesare Natali ITA-FIJE 90min 1g
- 2011-12-20 14y Fiorentina 0 at Siena 0
- 2011-09-25 15y Fiorentina 2 at Siena 1
- 2010-05-09 16y Siena 1 at Fiorentina 1
- 2010-01-06 16y Fiorentina 5 at Siena 1 Alberto Gilardino ITA-FIJE 90min 2g
- 2009-03-22 17y Siena 0 at Fiorentina 1 Sébastien Frey ITA-FIJE 90min
- 2008-11-02 17y Fiorentina 0 at Siena 1 Houssine Kharja ITA-SIEA 90min 1g
- 2008-03-09 18y Fiorentina 0 at Siena 1 Massimo Maccarone ITA-SIEA 90min 1g yc
- 2007-10-21 19y Siena 0 at Fiorentina 3 Adrian Mutu ITA-FIJE 90min 1g
- 2007-04-15 19y Siena 0 at Fiorentina 1 Adrian Mutu ITA-FIJE 90min 1g
- 2006-11-26 19y Fiorentina 1 at Siena 1
- 2006-03-05 20y Siena 1 at Fiorentina 2 Luca Toni ITA-FIJE 71min 1g
- 2005-10-26 20y Fiorentina 2 at Siena 0 Luca Toni ITA-FIJE 90min 2g
- 2005-02-19 21y Fiorentina 0 at Siena 1
- 2004-10-16 22y Siena 0 at Fiorentina 0